GeOx/Reduced Graphene Oxide Composite as an Anode for LiIon Batteries: Enhanced Capacity via Reversible Utilization of Li2O along with Improved Rate Performance
نویسندگان
چکیده
Anode materials with high specifi c capacity and rate capability are one of the key components of such batteries. Traditional carbon-based anode materials exhibit acceptable overall performance with respect to the energy/power requirements of existing portable electronic devices, but have a relatively low specifi c capacity, poor Li + insertion/extraction kinetics, and documented safety issues. [ 3 ] These downsides make carbon-based anodes inadequate for many upcoming applications and have impelled researchers to fi nd alternative high-capacity anode materials, for example, Si, Ge, and metal oxides. [ 4–7 ]
منابع مشابه
Rational Design of 1-D Co3O4 Nanofibers@Low content Graphene Composite Anode for High Performance Li-Ion Batteries
Cobalt oxide that has high energy density, is the next-generation candidate as the anode material for LIBs. However, the practical use of Co3O4 as anode material has been hindered by limitations, especially, low electrical conductivity and pulverization from large volume change upon cycling. These features lead to hindrance to its electrochemical properties for lithium-ion batteries. To improve...
متن کاملStable anode performance of vanadium oxide hydrate semi-microspheres and their graphene based composite microspheres in sodium-ion batteries.
A simple and versatile method for preparation of new crystalline vanadium oxide hydrate semi-microspheres is developed via a simple hydrothermal route, which are tested as a novel high-energy anode materials for sodium-ion batteries. The enhancement of electrochemical performance for the vanadium oxide hydrate electrode is offered by addition of graphene. The graphene-based vanadium oxide hydra...
متن کاملSynthesis of Mn3O4-Based Aerogels and Their Lithium-Storage Abilities
Mn3O4 aerogels and their graphene nanosheet (GN) composite aerogels were synthesized by a simple supercritical-ethanol process. In the process, supercritical ethanol acted as a reductant to reduce graphene oxide and MnO2 gels simultaneously. The synthesized aerogels consisted of 10-20 nm Mn3O4 nanocrystallites, with BET-specific surface areas around 60 m(2)/g. The performance of the aerogels as...
متن کاملUnique Cobalt Sulfide/Reduced Graphene Oxide Composite as an Anode for Sodium-Ion Batteries with Superior Rate Capability and Long Cycling Stability.
Exploitation of high-performance anode materials is essential but challenging to the development of sodium-ion batteries (SIBs). Among all proposed anode materials for SIBs, sulfides have been proved promising candidates due to their unique chemical and physical properties. In this work, a facile solvothermal method to in situ decorate cobalt sulfide (CoS) nanoplates on reduced graphene oxide (...
متن کاملElectrochemical properties of iron oxide nanoparticles as an anode for Li-ion batteries
The synthesis of iron oxide nano-particles by direct thermal decomposition was studied. Simultaneous thermal analysis and Fourier transform infrared spectroscopy results confirmed the formation of iron-urea complex, and disclosed iron oxide formation mechanism. Calcination of the iron-urea complex at 200°C and 250°C for 2 hrs. resulted in the formation of maghemite along with hematite as a seco...
متن کامل